On January 1, 1863, Mr. Charles M. Wolcott made a gift to the church of six acres of land adjacent to the St. Anna's burial ground. On May 15, 1866, Mr. Henry E. Davies donated an additional 6 acres of land adjacent to the 2 parcels fronting on Wolcott Avenue to make up what is now the 12+ acres of land St. Luke's is situated on. Plans for the structure. were prepared by Frederick C. Withers of New York and groundbreaking was held on August 10, 1868.
That same year, St. Anna's assumed the name St. Luke's Church, Matteawan. At that time the original church building was sold to the Methodist Church and the original Rectory was sold to Lewis Tompkins. On December 15, 1869 the church bell was rung for the first time, not only at St. Luke's, but as the first church bell in Matteawan. The first service in the new building was held on June 9, 1870 officiated by the Bishop and assisted by most of the clergy of the county.
The Rectory was constructed on the property in 1869 and 1870, but was destroyed by fire in 1887. The current Rectory was built shortly thereafter as an almost exact copy of the original. In 1892 construction began on what is the main structure of the current Parish House. The original plan called for a large building in the shape of a cross, but insufficient funds restricted the size and shape. In 1963, the Great Hall was built as an addition to the Parish House, thus bringing to reality the shape of the cross sought by the original planners.